UDK: 541.183.123.2

CALCULATION OF PARAMETERS OF A SOLUTION OF CROSSLINKED

POLYELECTROLYTE AT ION-EXCHANGE EQUILIBRIUM

Ferapontov N. B., Parbuzina L. R., Gorshkov V. I., Strusovskaya N. L.,

Gagarin A. N.

Department of Chemistry

M.V.Lomonosov Moscow State University

Moscow, 119899 Russia

Tel.: 939-4019

Fax: 939-0283

E-mail: fer@physch.chem.msu.su

The article is continuation of a cycle of clauses, in which on the basis

heterophase model of a structure of gel; the authors develop the theory of solutions of

cross-linked polyelectrolytes. The mathematical apparatus of calculation of such

parameters of builders of a solution of cross-linked polyelectrolyte, as amount,

concentration and activity is offered. Is shown, that at known properties of a solution

of monomer, from which the polyelectrolyte is synthesized, constants of distribution

of components present in both phases, the composition of an exterior equilibrium

solution of low molecular weight electrolyte, is possible to calculate all listed above

parameters.